![]() Plant defoliating agent
专利摘要:
New compositions for defoliating plants possessed of synergistic activity comprising (A) a compound of formula I <IMAGE> I in which R1 is hydrogen or C1-C4-alkyl, R2 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy or C1-C4-alkylthio, R3 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkylthio or C3-C8-cycloalkyl, wherein R2 and R3 taken together with the nitrogen atom to which they are attached is a morpholino- piperidino- or pyrrolidino-group, X is oxygen or sulfur, Y can be the same or different and is hydrogen, halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C2-alkyl, C1-C4-alkylthio, trifluoromethyl or nitro, and n is the number 1, 2, 3, 4 or 5, in combination with (B) a defoliant for plants in a proportion of 1 to 99 parts by weight of component (A) to 99 to 1 parts by weight of component (B). As the defoliant there can be employed 1,2,3-thiadiazole-5-yl-urea derivatives, 1,2,3-thiadiazole-5-carboxylic acid derivatives, benzylaminopurine derivatives, 2,3-dihydro-5,6-dimethyl-1,4-dithiine-1,1,4,4-tetroxide, 1,1'-dimethyl-4,4'-bipyridilium-dichloride, sodium chlorate and S,S,S-tributylphosphortrithioate. The compositions of the invention are especially suitable for use in the defoliation of cotton plants. 公开号:SU1327781A3 申请号:SU833600946 申请日:1983-06-09 公开日:1987-07-30 发明作者:Руш Райнхарт 申请人:Шеринг Аг (Фирма); IPC主号:
专利说明:
ten 1327781 The invention relates to rural. This means, in particular, the means of defoliation of plants. The purpose of the invention is to increase the de-oliation activity of a known compound containing K-phenyl-M - (1, 2, 3-thiadiazolyl-5) -urea (Compound A). As a synergist, the composition according to the invention contains the known herbicide diuron K- (3,4-dichlorophenyl) -N, N -dimethylurea. Example 1. Young cotton plants in the stage of 5-7 developing green leaves were treated with the above components or their mixture (repeated 4 times). After 2 weeks the percentage of leaf leaves was established. The results are shown in table 1. Example 2. Young cotton plants in the stage of 5-8 developing green leaves were processed and evaluated as in example 1 (see Table 2). Example 3. Young cotton plants in stage 4-6 of the developed green leaves were processed and evaluated15 20 25 me with that zea with de to measure F on the c nh to m were recorded as in Example 1 (see Table 3). Example 4. Young cotton plants in the stage of 5-6 developed green leaves were treated and evaluated as in example 1 (see Table 4). Example 5. Young cotton plants in the stage of 4-6 developed green leaves were treated with yjKa3aH components below or their mixture (repeated 4 times). The applied amounts of spray solution corresponded to 500 L / ha. A few days after the treatment with active substances (when one substance had not yet reached the leaves of the leaves), the percentage of leaves that had flown around was determined. Tab. 5 shows the above-mentioned rate of action of the agent according to the invention. five 0 Example 6. Young cotton plants in the stage of 5–7 developed green leaves were treated as in example 5, and with the beginning of the fall of greenery, one substance A was assessed (see Table 6). Example 7. Hibicus seedlings with formed roots and with a height of 20-30 cm of shoots and 8-10 green leaves were processed with the components named below or their mixtures and evaluated after one and a half weeks (see Table 7p. In tab. 8 shows the content of the components of compounds A and B in examples 1-7, depending on the norm.
权利要求:
Claims (1) [1] Invention Formula Plant defoliation agent containing N-phenyl-K - (1,2, 3-thiadiazolyl-5) -urea (A), surfactant and carrier, t 5 about 35 40 45 In order to increase the defoliating activity, it additionally contains N- (3,4-dichlorophene) -N, N -dimethylurea (c) in the ratio A: B equal to 10: 1-1: 40, and as a surface-active mixture calcium and sodium salt M-methylgN-oleyl taurine, as a carrier is magnesium-aluminum silicate in the following ratio of components, wt.%: N-phenyl-N (1,2,3-thiadiazolyl-3) -urea 0, 49-18,8 N- (3,4-Dichloro- phenyl) -N, N dimethylurea 1.82-19.51 Ligninsulfonate Calcium 8.0 oleyl salt 2.0 Else N-Phenyl-S (1,2,3-thiadiazolyl-5) -urea (A) N- (3,4-Dichlorophenyl) - N, N -dimethylurea (B) A + B (1:10) (1: 5) M-Phenyl-K - (1,2,3-thiadiazol-1-5) -urea (A) N- (3,4-Dichlorophenyl) - N, N -dimethylurea (B) A + B (1: 1.5) Table 1 10 14 33 ABOUT 57 81 (10) (14) table 2 (12) Consumption Defoliatsi, E (at the norm of com-% Colby) ponent, g / ha - 80 32 200O 40 + 40100 Table 4 Expendable Defoliatsi, E (by norm com-% Colby) pontoon, g / ha 50 33 500 o 50 + 100 95 (33) So blitz 5 Consumption Defoliatsi, E (at the norm of com-% Colby) ponent, g / ha .20 About 160 Oh N- (3,4-Dichlorophenyl) - N, N -dimethylurea (B) A + B (1:40) Table 3 ABOUT 70 45 Components N-Phenyl-K - (1,2,3-thiadiazolyl-5) -urea (A) N- (3,4-Dichlorophenyl) - N, N -dimethylurea (B) A + B (2: 1) Table 7 Expendable Defoliatsi, E (by the rate of com-% Colby) ponenta, g / ha 5 33 -50О 5 + 3041 (33) Table 8 normal rate- Content of the components A and + B B, respectively, wt.% 10 + 100 20 + 100 20 + 30 40 + 40 Table 6 Defolianci, four 13 17 About 79 1.82 and 18.18 3.33 and 16.67 8 and 12 10 and 10 50 + 100 100 + 10 10 + 400 30 + 15 5 + 30 6.67 and 13.33 18.18 and 1.82 0.49 and 19.51 13.33 and 6.67 2.86 and 17.14
类似技术:
公开号 | 公开日 | 专利标题 SU1327781A3|1987-07-30|Plant defoliating agent ES8402575A1|1984-03-01|Phenyl urea. ES474029A1|1980-01-16|N-|-N'-phenylureas, methods for their preparation and plant growth regulators containing them. ES8105249A1|1981-06-16|Novel substituted nitrodiphenyl ethers, herbicidal compositions containing them, processes for the preparation thereof and the use thereof for combating weeds. SU1284457A3|1987-01-15|Agent for defoliating cotton plants ES8302660A1|1983-02-01|Pyridine and pyrazine derivatives, preparation of these compounds, fungicidal agents containing these compounds as active ingredients, and the use of such compounds or agents as fungicides in agriculture and in horticulture. SU741772A3|1980-06-15|Fungicidic agent JPS58164502A|1983-09-29|Herbicidal composition SU670194A3|1979-06-25|Herbicide ES481029A1|1980-08-16|Herbicidal carbamimidothioates, preparation and use thereof and compositions containing said compounds. US3632646A|1972-01-04|Succinamides IL32022A|1973-03-30|N-|-n'-methyl-n'-methoxyurea,its manufacture and its use as herbicide SU667099A3|1979-06-05|Herbicide US3285730A|1966-11-15|Method for controlling plant growth SU440815A1|1974-08-25|HERBICIDE STRUCTURE US2923727A|1960-02-02|O-alkyl-s-pentachlorophenyl thiolcarbonate SU1028235A3|1983-07-07|Herbicidal composition GB1041011A|1966-09-01|Fungicidal compositions and halogenated quinoxalines US4936899A|1990-06-26|Abscission of parts of plants US3906062A|1975-09-16|Alpha,alpha-diphosphonato acetanilides SU639410A3|1978-12-25|Herbicide JPS58124707A|1983-07-25|Herbicide SU1264830A3|1986-10-15|Fungicide agent US3759689A|1973-09-18|Method forregulating plant growth SU1340569A3|1987-09-23|Insecticide composition
同族专利:
公开号 | 公开日 DK266883D0|1983-06-10| US4613354A|1986-09-23| GB2121686B|1986-05-21| IT1165452B|1987-04-22| MA19810A1|1983-12-31| LU84854A1|1983-11-17| ZW13583A1|1983-09-14| GB8315462D0|1983-07-13| BE897029A|1983-12-12| IN159301B|1987-05-02| IT8321487D0|1983-06-07| NL8301883A|1984-01-02| AU1529583A|1984-12-13| DE3222622A1|1983-12-15| TR21718A|1985-04-17| IL68918A|1987-03-31| GR77538B|1984-09-24| EG16471A|1994-07-30| ZA834282B|1984-03-28| BR8303101A|1984-01-31| GB2121686A|1984-01-04| DK266883A|1983-12-12| AU565869B2|1987-10-01| FR2528280A1|1983-12-16|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 BE548038A|1955-05-23| US2954467A|1958-01-30|1960-09-27|Hughes Aircraft Co|Gating circuit| GB1088982A|1963-04-29|1967-10-25|Ici Ltd|Herbicidal compositions| IL36220D0|1970-02-27|1971-04-28|Ciba Geigy Ag|Use of a phenylurea for combating weeds in wheat,oats,rye,barley,rice and cotton| DE2039041A1|1970-08-06|1972-02-17|Hoechst Ag|Herbicides| SU472488A3|1971-10-29|1975-05-30|Лиценция Талалманиокат Эртекезито Валалат |Defoliant| FR2215898B1|1973-02-02|1977-04-22|Philagro Sa| DK581374A|1973-11-16|1975-07-21|Ici Ltd| GB1502259A|1974-02-18|1978-03-01|Ici Ltd|Herbicidal formulations| DE2506690A1|1975-02-14|1976-09-02|Schering Ag|Means for removing leaves from plants| DE2619861C2|1976-05-03|1985-05-09|Schering AG, 1000 Berlin und 4709 Bergkamen|1- -3- urea and agents containing these for regulating growth and for removing leaves from plants| DE2646712C2|1976-10-14|1988-02-04|Schering Ag, 1000 Berlin Und 4709 Bergkamen, De| DE2745968A1|1977-10-10|1979-04-19|Schering Ag|Defoliant compsn. esp. for cotton - contains synergistic mixt. of thiadiazolyl-urea and di:phenyl-urea, or thio analogues| GB2017495A|1978-02-23|1979-10-10|Sandoz Ltd|Defoliation compositions| NL7901292A|1978-02-23|1979-08-27|Sandoz Ag|METHOD FOR THE PREPARATION OF A DEBLADING PREPARATION AND FOR THE DEBLADING OF LEAF-BEARING CROPS THEREFORE.| GB2074448B|1980-03-19|1983-06-08|Murphy Chemical Ltd|Selective weed control and compostions therefor| GB2078519B|1980-06-19|1983-08-03|May & Baker Ltd|Weed control using 3--1,1-dimethylurea in conjunction with s-2,3,3-trichloroallyl diisopropylthiocarbamate| CH645515A5|1981-02-19|1984-10-15|Siegfried Ag|MEDIA FOR LEAVING CULTIVATED PLANTS.|US4846872A|1986-08-11|1989-07-11|Fujisawa Pharmaceutical Co., Ltd.|Herbicide| IL84804D0|1986-12-18|1988-06-30|Schering Ag|Plant defoliant compositions containing thiadiazole urea derivative and azacylcloheptane derivative and process for the preparation thereof| IL84803A|1986-12-18|1991-01-31|Schering Ag|Plant defoliant compositions containing thiadiazole urea derivative,a carboxamide or tributyl phosphate and halophenyl dialkyl urea derivative and process for the preparation thereof| DE3919037A1|1989-06-10|1990-12-13|Hoechst Ag|LIQUID HERBICIDAL MIXTURE| US5238905A|1991-10-28|1993-08-24|Union Oil Company Of California|Plant control composition and methods of use with thidiazuron and monocarbamide dihydrogen sulfate| AR022889A1|1999-03-12|2002-09-04|Bayer Cropscience Ag|DEFROLING AGENT| DE19911165B4|1999-03-12|2008-03-13|Bayer Cropscience Ag|defoliants| US6562758B1|1999-12-15|2003-05-13|Basf Corporation|Methods and compositions to defoliate crop plants and minimize plant regrowth following defoliation| DE102006009101A1|2006-02-24|2007-09-06|Bayer Cropscience Gmbh|defoliant| US20070203025A1|2006-02-24|2007-08-30|Udo Bickers|Defoliant| EP1985180A1|2007-04-25|2008-10-29|Bayer CropScience AG|Defoliant| EP2238834A1|2009-04-07|2010-10-13|Bayer CropScience Aktiengesellschaft|Defoliant based on thidiazuron and 1,2,4-triazinones| EP2238835B1|2009-04-07|2016-04-06|Bayer Intellectual Property GmbH|Defoliant based on thidiazuron and flufenacet| PT2861074T|2012-05-25|2017-10-02|Lanxess Distrib Gmbh|Thinner containing diuron| CN106070279A|2016-06-03|2016-11-09|华南农业大学|One plant growth regulators Thidiazuron diuron electrostatic liquor and making, purposes and using method| US20200296969A1|2017-11-17|2020-09-24|Upl Ltd|Novel combinations of defoliants|
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申请号 | 申请日 | 专利标题 DE19823222622|DE3222622A1|1982-06-11|1982-06-11|AGENT FOR DE-LEAVING PLANTS WITH SYNERGISTIC EFFECT| 相关专利
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